Bis(4-hydroxybenzoato-κ2 O,O′)bis(pyridine-κN)copper(II)
نویسندگان
چکیده
In the title compound, [Cu(C(7)H(5)O(3))(2)(C(5)H(5)N)(2)], the Cu atom is located on an inversion center and is coordinated by the N atoms of the two pyridine ligands, trans to each other, and to the carboxyl-ate O atoms of two bidentate 4-hy-droxy-benzoate ligands [Cu-O = 1.9706 (10) and 2.5204 (11) Å]. Hydrogen bonding between hy-droxy H and carboxyl-ate O atoms results in a layer structure parallel to the ab plane.
منابع مشابه
Bis(μ-3-hydroxybenzoato)-κ3 O 1,O 1′:O 1;κ3 O 1:O 1,O 1′-bis[(3-hydroxybenzoato-κ2 O,O′)(isonicotinamide-κN 1)cadmium] tetrahydrate
In the title centrosymmetric binuclear Cd(II) compound, [Cd(2)(C(7)H(5)O(3))(4)(C(6)H(6)N(2)O)(2)]·4H(2)O, the six-coordinated Cd(II) atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl-ate groups. In the crystal, O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a th...
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